Lanthanum

57 bariumlanthanumcerium
-

La

Ac
Periodic Table - Extended Periodic Table
General
Name, Symbol, Number lanthanum, La, 57
Chemical series lanthanides
Group, Period, Block 3, 6, f
Appearance silvery white
Atomic mass 138.90547(7) g/mol
Electron configuration [Xe] 5d1 6s2
Electrons per shell 2, 8, 18, 18, 9, 2
Physical properties
Phase solid
Density (near r.t.) 6.162 g·cm−3
Liquid density at m.p. 5.94 g·cm−3
Melting point 1193 K
(920 °C, 1688 °F)
Boiling point 3737 K
(3464 °C, 6267 °F)
Heat of fusion 6.20 kJ·mol−1
Heat of vaporization 402.1 kJ·mol−1
Heat capacity (25 °C) 27.11 J·mol−1·K−1
Vapor pressure (extrapolated)
P/Pa 1 10 100 1 k 10 k 100 k
at T/K 2005 2208 2458 2772 3178 3726
Atomic properties
Crystal structure hexagonal
Oxidation states 3
(strongly basic oxide)
Electronegativity 1.10 (Pauling scale)
Ionization energies
(more)
1st: 538.1 kJ·mol−1
2nd: 1067 kJ·mol−1
3rd: 1850.3 kJ·mol−1
Atomic radius 195 pm
Covalent radius 169 pm
Miscellaneous
Magnetic ordering  ?
Electrical resistivity (r.t.) (α, poly) 615 nΩ·m
Thermal conductivity (300 K) 13.4 W·m−1·K−1
Thermal expansion (r.t.) (α, poly)
12.1 µm/(m·K)
Speed of sound (thin rod) (20 °C) 2475 m/s
Young's modulus (α form) 36.6 GPa
Shear modulus (α form) 14.3 GPa
Bulk modulus (α form) 27.9 GPa
Poisson ratio (α form) 0.280
Mohs hardness 2.5
Vickers hardness 491 MPa
Brinell hardness 363 MPa
CAS registry number 7439-91-0
Selected isotopes
Main article: Isotopes of lanthanum
iso NA half-life DM DE (MeV) DP
137La syn 60,000 yrs ε 0.600 137Ba
138La 0.09% 105×109yrs ε 1.737 138Ba
β- 1.044 138Ce
139La 99.91% La is stable with 82 neutrons
References

Lanthanum (IPA: /ˈlanθənəm/) is a chemical element in the periodic table that has the symbol La and atomic number 57.

Contents

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Notable characteristics

Lanthanum.
Lanthanum.

Lanthanum is a silvery white metallic element belonging to group 3 of the periodic table and often considered to be one of the lanthanides. Found in some rare-earth minerals, usually in combination with cerium and other rare earth elements. Lanthanum is malleable, ductile, and soft enough to be cut with a knife. It is one of the most reactive of the rare-earth metals. The metal reacts directly with elemental carbon, nitrogen, boron, selenium, silicon, phosphorus, sulfur, and with halogens. It oxidizes rapidly when exposed to air. Cold water attacks lanthanum slowly, while hot water attacks it much more rapidly.

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Applications

Uses of lanthanum:

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History

Lanthanum was discovered in 1839 by Swedish chemist Carl Gustav Mosander, when he partially decomposed a sample of cerium nitrate by heating and treating the resulting salt with dilute nitric acid. From the resulting solution, he isolated a new rare earth he called lantana. Lanthanum was isolated in relatively pure form in 1923.

The word lanthanum comes from the Greek λανθανω [lanthanō] = to lie hidden.

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Biological Role

Lanthanum has no known biological role. The element is not absorbed orally, and when injected its elimination is very slow. Lanthanum carbonate was approved as a medication (Fosrenol®, Shire Pharmaceuticals) to absorb excess phosphate in cases of end-stage renal failure. Some rare-earth chlorides, such as lanthanum chloride (LaCl3), are known to have anticoagulant properties.

While Lanthanum has pharmacological effects on several receptors and ion channels its specificity for the GABA receptor is unique among divalent cations. Lanthanum acts at the same modulatory site on the GABAR as zinc- a known negative allosteric modulator. The Lanthanum cation La3+ is a positive allosteric modulator at native and recombinant GABA receptors, increasing open channel time and decreasing desensitization in a subunit configuration dependent manner.

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Occurrence

Although lanthanum belongs to chemical elements group called rare earth metals, it is not rare at all. Lanthanum is available in relatively large quantities (32 ppm in Earth’s crust).

Monazite (Ce, La, Th, Nd, Y)PO4, and bastnasite (Ce, La, Y)CO3F, are principal ores in which lanthanum occurs in percentages up to 25 to 38 percent.

See also category:Lanthanide minerals

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Isotopes

Naturally occurring lanthanum is composed of one stable (139La) and one radioactive (138La) isotope, with the stable isotope, 139La, being the most abundant (99.91% natural abundance). 38 radioisotopes have been characterized with the most stable being 138La with a half-life of 105×109 years, and 137La with a half-life of 60,000 years. All of the remaining radioactive isotopes have half-lives that are less than 24 hours and the majority of these have half lives that are less than 1 minute. This element also has 3 meta states.

The isotopes of lanthanum range in atomic weight from 117 u (117La) to 155 u (155La).

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Precautions

Lanthanum has a low to moderate level of toxicity, and should be handled with care. In animals, the injection of lanthanum solutions produces glycaemia, low blood pressure, degeneration of the spleen and hepatic alterations.

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References

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External links

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