Density

Density
Common symbols
ρ
D
SI unit kg/m3
A graduated cylinder containing various coloured liquids with different densities

The density, or more precisely, the volumetric mass density, of a substance is its mass per unit volume. The symbol most often used for density is ρ (the lower case Greek letter rho), although the Latin letter D can also be used. Mathematically, density is defined as mass divided by volume:[1]

where ρ is the density, m is the mass, and V is the volume. In some cases (for instance, in the United States oil and gas industry), density is loosely defined as its weight per unit volume,[2] although this is scientifically inaccurate – this quantity is more specifically called specific weight.

For a pure substance the density has the same numerical value as its mass concentration. Different materials usually have different densities, and density may be relevant to buoyancy, purity and packaging. Osmium and iridium are the densest known elements at standard conditions for temperature and pressure but certain chemical compounds may be denser.

To simplify comparisons of density across different systems of units, it is sometimes replaced by the dimensionless quantity "relative density" or "specific gravity", i.e. the ratio of the density of the material to that of a standard material, usually water. Thus a relative density less than one means that the substance floats in water.

The density of a material varies with temperature and pressure. This variation is typically small for solids and liquids but much greater for gases. Increasing the pressure on an object decreases the volume of the object and thus increases its density. Increasing the temperature of a substance (with a few exceptions) decreases its density by increasing its volume. In most materials, heating the bottom of a fluid results in convection of the heat from the bottom to the top, due to the decrease in the density of the heated fluid. This causes it to rise relative to more dense unheated material.

The reciprocal of the density of a substance is occasionally called its specific volume, a term sometimes used in thermodynamics. Density is an intensive property in that increasing the amount of a substance does not increase its density; rather it increases its mass.

History

In a well-known but probably apocryphal tale, Archimedes was given the task of determining whether King Hiero's goldsmith was embezzling gold during the manufacture of a golden wreath dedicated to the gods and replacing it with another, cheaper alloy.[3] Archimedes knew that the irregularly shaped wreath could be crushed into a cube whose volume could be calculated easily and compared with the mass; but the king did not approve of this. Baffled, Archimedes is said to have taken an immersion bath and observed from the rise of the water upon entering that he could calculate the volume of the gold wreath through the displacement of the water. Upon this discovery, he leapt from his bath and ran naked through the streets shouting, "Eureka! Eureka!" (Εύρηκα! Greek "I have found it"). As a result, the term "eureka" entered common parlance and is used today to indicate a moment of enlightenment.

The story first appeared in written form in Vitruvius' books of architecture, two centuries after it supposedly took place.[4] Some scholars have doubted the accuracy of this tale, saying among other things that the method would have required precise measurements that would have been difficult to make at the time.[5][6]

From the equation for density (ρ = m/V), mass density has units of mass divided by volume. As there are many units of mass and volume covering many different magnitudes there are a large number of units for mass density in use. The SI unit of kilogram per cubic metre (kg/m3) and the cgs unit of gram per cubic centimetre (g/cm3) are probably the most commonly used units for density. One g/cm3 is equal to one thousand kg/m3. One cubic centimetre (abbreviation cc) is equal to one millilitre. In industry, other larger or smaller units of mass and or volume are often more practical and US customary units may be used. See below for a list of some of the most common units of density.

Measurement of density

Homogeneous materials

The density at all points of a homogeneous object equals its total mass divided by its total volume. The mass is normally measured with a scale or balance; the volume may be measured directly (from the geometry of the object) or by the displacement of a fluid. To determine the density of a liquid or a gas, a hydrometer, a dasymeter or a Coriolis flow meter may be used, respectively. Similarly, hydrostatic weighing uses the displacement of water due to a submerged object to determine the density of the object.

Heterogeneous materials

If the body is not homogeneous, then its density varies between different regions of the object. In that case the density around any given location is determined by calculating the density of a small volume around that location. In the limit of an infinitesimal volume the density of an inhomogeneous object at a point becomes: , where is an elementary volume at position . The mass of the body then can be expressed as

Non-compact materials

In practice, bulk materials such as sugar, sand, or snow contain voids. Many materials exist in nature as flakes, pellets, or granules.

Voids are regions which contain something other than the considered material. Commonly the void is air, but it could also be vacuum, liquid, solid, or a different gas or gaseous mixture.

The bulk volume of a material—inclusive of the void fraction—is often obtained by a simple measurement (e.g. with a calibrated measuring cup) or geometrically from known dimensions.

Mass divided by bulk volume determines bulk density. This is not the same thing as volumetric mass density.

To determine volumetric mass density, one must first discount the volume of the void fraction. Sometimes this can be determined by geometrical reasoning. For the close-packing of equal spheres the non-void fraction can be at most about 74%. It can also be determined empirically. Some bulk materials, however, such as sand, have a variable void fraction which depends on how the material is agitated or poured. It might be loose or compact, with more or less air space depending on handling.

In practice, the void fraction is not necessarily air, or even gaseous. In the case of sand, it could be water, which can be advantageous for measurement as the void fraction for sand saturated in water—once any air bubbles are thoroughly driven out—is potentially more consistent than dry sand measured with an air void.

In the case of non-compact materials, one must also take care in determining the mass of the material sample. If the material is under pressure (commonly ambient air pressure at the earth's surface) the determination of mass from a measured sample weight might need to account for buoyancy effects due to the density of the void constituent, depending on how the measurement was conducted. In the case of dry sand, sand is so much denser than air that the buoyancy effect is commonly neglected (less than one part in one thousand).

Mass change upon displacing one void material with another while maintaining constant volume can be used to estimate the void fraction, if the difference in density of the two voids materials is reliably known.

Changes of density

In general, density can be changed by changing either the pressure or the temperature. Increasing the pressure always increases the density of a material. Increasing the temperature generally decreases the density, but there are notable exceptions to this generalization. For example, the density of water increases between its melting point at 0 °C and 4 °C; similar behavior is observed in silicon at low temperatures.

The effect of pressure and temperature on the densities of liquids and solids is small. The compressibility for a typical liquid or solid is 10−6 bar−1 (1 bar = 0.1 MPa) and a typical thermal expansivity is 10−5 K−1. This roughly translates into needing around ten thousand times atmospheric pressure to reduce the volume of a substance by one percent. (Although the pressures needed may be around a thousand times smaller for sandy soil and some clays.) A one percent expansion of volume typically requires a temperature increase on the order of thousands of degrees Celsius.

In contrast, the density of gases is strongly affected by pressure. The density of an ideal gas is

where M is the molar mass, P is the pressure, R is the universal gas constant, and T is the absolute temperature. This means that the density of an ideal gas can be doubled by doubling the pressure, or by halving the absolute temperature.

In the case of volumic thermal expansion at constant pressure and small intervals of temperature the temperature dependence of density is :

where is the density at a reference temperature, is the thermal expansion coefficient of the material at temperatures close to .

Density of solutions

The density of a solution is the sum of mass (massic) concentrations of the components of that solution.

Mass (massic) concentration of each given component ρi in a solution sums to density of the solution.

Expressed as a function of the densities of pure components of the mixture and their volume participation, it allows the determination of excess molar volumes:

provided that there is no interaction between the components.

Knowing the relation between excess volumes and activity coefficients of the components, one can determine the activity coefficients.

Densities

Various materials

Densities of various materials covering a range of values
Material ρ (kg/m3)[note 1] Notes
Hydrogen0.0898
Helium0.179
Aerographite0.2[note 2][7][8]
Metallic microlattice0.9[note 2]
Aerogel1.0[note 2]
Air1.2At sea level
Tungsten hexafluoride12.4One of the heaviest known gases at standard conditions
Liquid hydrogen70At approx. −255 °C
Styrofoam75Approx.[9]
Cork240Approx.[9]
Pine373[10]
Lithium535
Wood700Seasoned, typical[11][12]
Oak710[10]
Potassium860[13]
Ice916.7At temperature < 0 °C
Cooking oil910...930
Sodium970
Water (fresh)1,000At 4 °C, the temperature of its maximum density
Water (salt)1,0300.9%
Liquid oxygen1,141At approx. −219 °C
Nylon1,150
Plastics1,175Approx.; for polypropylene and PETE/PVC
Tetrachloroethene1,622
Magnesium1,740
Beryllium1,850
Glycerol1,261[14]
Concrete2,400[15][16]
Silicon2,330
Aluminium2,700
Diiodomethane3,325Liquid at room temperature
Diamond3,500
Titanium4,540
Selenium4,800
Vanadium6,100
Antimony6,690
Zinc7,000
Chromium7,200
Tin7,310
Manganese7,325Approx.
Iron7,870
Niobium8,570
Brass8,600[16]
Cadmium8,650
Cobalt8,900
Nickel8,900
Copper8,940
Bismuth9,750
Molybdenum10,220
Silver10,500
Lead11,340
Thorium11,700
Rhodium12,410
Mercury13,546
Tantalum16,600
Uranium18,800
Tungsten19,300
Gold19,320
Plutonium19,840
Rhenium21,020
Platinum21,450
Iridium22,420
Osmium22,570
Notes:
  1. Unless otherwise noted, all densities given are at standard conditions for temperature and pressure,
    that is, 273.15 K (0.00 °C) and 100 kPa (0.987 atm).
  2. 1 2 3 Air contained in material excluded when calculating density

Others

Entity ρ (kg/m3) Notes
Interstellar medium1×10−19Assuming 90% H, 10% He; variable T
The Earth5,515Mean density.[17]
The inner core of the Earth13,000Approx., as listed in Earth.[18]
The core of the Sun33,000–160,000Approx.[19]
Super-massive black hole9×105Density of a 4.5-million-solar-mass black hole
Event horizon radius is 13.5 million km.
White dwarf star2.1×109Approx.[20]
Atomic nuclei2.3×1017Does not depend strongly on size of nucleus[21]
Neutron star1×1018
Stellar-mass black hole1×1018Density of a 4-solar-mass black hole
Event horizon radius is 12 km.

Water

Density of liquid water at 1 atm pressure
Temp. (°C)[note 1] Density (kg/m3)
−30983.854
−20993.547
−10998.117
0999.8395
4999.9720
10999.7026
15999.1026
20998.2071
22997.7735
25997.0479
30995.6502
40992.2
60983.2
80971.8
100958.4
Notes:
  1. Values below 0 °C refer to supercooled water.

Air

Air density vs. temperature
Density of air at 1 atm pressure
T (°C) ρ (kg/m3)
−251.423
−201.395
−151.368
−101.342
−51.316
01.293
51.269
101.247
151.225
201.204
251.184
301.164
351.146

Molar volumes of liquid and solid phase of elements

Molar volumes of liquid and solid phase of elements

Common units

The SI unit for density is:

The litre and metric tons are not part of the SI, but are acceptable for use with it, leading to the following units:

Densities using the following metric units all have exactly the same numerical value, one thousandth of the value in (kg/m3). Liquid water has a density of about 1 kg/dm3, making any of these SI units numerically convenient to use as most solids and liquids have densities between 0.1 and 20 kg/dm3.

  • kilogram per cubic decimetre (kg/dm3)
  • gram per cubic centimetre (g/cm3)
    • 1 g/cm3 = 1000 kg/m3
  • megagram (metric ton) per cubic metre (Mg/m3)

In US customary units density can be stated in:

  • Avoirdupois ounce per cubic inch (1 g/cc ≈ 0.578036672 oz/cu in)
  • Avoirdupois ounce per fluid ounce (1 g/cc ≈ 1.04317556 oz/fl. oz = 1.04317556 lbs/pint)
  • Avoirdupois pound per cubic inch (1 g/cc ≈ 0.036127292 lb/cu in)
  • pound per cubic foot (1 g/cc ≈ 62.427961 lb/cu ft)
  • pound per cubic yard (1 g/cc ≈ 1685.5549 lb/cu yd)
  • pound per US liquid gallon (1 g/cc ≈ 8.34540445 lb/gal)
  • pound per US bushel (1 g/cc ≈ 77.6888513 lb/bu)
  • slug per cubic foot

Imperial units differing from the above (as the Imperial gallon and bushel differ from the US units) in practice are rarely used, though found in older documents. The Imperial gallon was based on the concept that an Imperial fluid ounce of water would have a mass of one Avoirdupois ounce, and indeed 1 g/cc ≈ 1.00224129 ounces per Imperial fluid ounce = 10.0224129 pounds per Imperial gallon. The density of precious metals could conceivably be based on Troy ounces and pounds, a possible cause of confusion.

See also

References

  1. The National Aeronautic and Atmospheric Administration's Glenn Research Center. "Gas Density Glenn research Center". grc.nasa.gov. Archived from the original on April 14, 2013.
  2. "Density definition in Oil Gas Glossary". Oilgasglossary.com. Archived from the original on August 5, 2010. Retrieved September 14, 2010.
  3. Archimedes, A Gold Thief and Buoyancy Archived August 27, 2007, at the Wayback Machine. – by Larry "Harris" Taylor, Ph.D.
  4. Vitruvius on Architecture, Book IX, paragraphs 9–12, translated into English and in the original Latin.
  5. "EXHIBIT: The First Eureka Moment". Science. 305 (5688): 1219e. 2004. doi:10.1126/science.305.5688.1219e.
  6. Fact or Fiction?: Archimedes Coined the Term "Eureka!" in the Bath, Scientific American, December 2006.
  7. New carbon nanotube struructure aerographite is lightest material champ Archived October 17, 2013, at the Wayback Machine.. Phys.org (July 13, 2012). Retrieved on July 14, 2012.
  8. Aerographit: Leichtestes Material der Welt entwickelt – SPIEGEL ONLINE Archived October 17, 2013, at the Wayback Machine.. Spiegel.de (July 11, 2012). Retrieved on July 14, 2012.
  9. 1 2 "Re: which is more bouyant [sic] styrofoam or cork". Madsci.org. Archived from the original on February 14, 2011. Retrieved September 14, 2010.
  10. 1 2 Raymond Serway; John Jewett (2005), Principles of Physics: A Calculus-Based Text, Cengage Learning, p. 467, ISBN 0-534-49143-X, archived from the original on May 17, 2016
  11. "Wood Densities". www.engineeringtoolbox.com. Archived from the original on October 20, 2012. Retrieved October 15, 2012.
  12. "Density of Wood". www.simetric.co.uk. Archived from the original on October 26, 2012. Retrieved October 15, 2012.
  13. CRC Press Handbook of tables for Applied Engineering Science, 2nd Edition, 1976, Table 1-59
  14. glycerol composition at Archived February 28, 2013, at the Wayback Machine.. Physics.nist.gov. Retrieved on July 14, 2012.
  15. 1 2 Hugh D. Young; Roger A. Freedman. University Physics with Modern Physics Archived April 30, 2016, at the Wayback Machine.. Addison-Wesley; 2012. ISBN 978-0-321-69686-1. p. 374.
  16. Density of the Earth, wolframalpha.com, archived from the original on October 17, 2013
  17. Density of Earth's core, wolframalpha.com, archived from the original on October 17, 2013
  18. Density of the Sun's core, wolframalpha.com, archived from the original on October 17, 2013
  19. Extreme Stars: White Dwarfs & Neutron Stars Archived September 25, 2007, at the Wayback Machine., Jennifer Johnson, lecture notes, Astronomy 162, Ohio State University. Accessed: May 3, 2007.
  20. Nuclear Size and Density Archived July 6, 2009, at the Wayback Machine., HyperPhysics, Georgia State University. Accessed: June 26, 2009.
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